. 2025

428

Modulating Adsorption Kinetics in a 3D-Interconnected Nanocavity Framework with Narrow Apertures for Enhanced Propylene Separation

Long-Zhang Dong, Zi-Yi Liao, Ling-Xiang Bao, Ming-Chan Yang, Bo Bai, Bao Yuan, Run-Han Li, Ping Miao, Yong Yan* and Ya-Qian Lan*. Journal of the American Chemical Society, 2025, 147(22): 18993-19003.

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427

Constructing Dual-Functional Organic Cuboctahedron Cages with Two Different Triangular Building Units for Efficient Artificial Photosynthesis of Hydrogen Peroxide from Water and Oxygen

Lei Zhang, Zihao Chen, Xiao-Xin Li, Xiang Wang, Qianfeng Gu, Zongmin Zheng, Naoki Aratani*, Chun-Sing Lee*, Ya-Qian Lan* and Qichun Zhang*. Journal of the American Chemical Society, 2025, 147(31): 27847-27854.

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426

Binuclear Metal-Based Covalent Organic Framework Mimicking Metallohydrolases for Direct Photoreforming of PET Plastic

Ming-Hao Qin, Pei Huang, Mi Zhang, Cheng Xiao, Jia-Yi Chen, Yi-Da Zhou, Meng Lu*, Ji-Yang Li* and Ya-Qian Lan*. Journal of the American Chemical Society, 2025, 147(32): 29232-29240.

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425

Hollow Giant Polyoxometalate Oxidation Shell Encapsulating Molecular Reduction Core for Unprecedented Photoredox Cascade Conversion

Xiang-Dong Xie, Jing-Jing Liu, Jiao-Min Lin*, Ning Li, Xiao-Hong Chen, Xian-Ye Lin, Yu-Ting Hao, Shun-Li Li, Jiang Liu* and Ya-Qian Lan*. Chem, 2025, 102572.

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424

Solid‐Liquid‐Gas Three‐Phase Indirect Electrolysis Enabled by Affinity Auxiliary Imparted Covalent Organic Frameworks

Yi-Rong Wang, Ming Yue, Gang Liu, Jia-Li Zhang, Qi Li, Jing-Wen Shi, Jia-Yong Weng, Run-Han Li, Yifa Chen*, Shun-Li Li and Ya-Qian Lan*. Angewandte Chemie International Edition, 2025, 64(1): e202413030.

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423

Dual Metallosalen-based Covalent Organic Frameworksfor Artificial Photosynthetic Diluted CO2 Reduction

Hong Dong, Liang Fang, Ke-Xin Chen, jian-Xin Wei, jia-Xin Li, Xiu Qiao, Ya Wang, Feng-Ming Zhang* and Ya-Qian Lan*. Angewandte Chemie International Edition, 2025, 64(2): e202414287.

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422

Interweavable Metalloporphyrin-based Fibers for Indirect Electrocatalysis

Xiaoman Yao, Gang Liu, Yingying Huang, Caier Huang, Xuanxu Chen, Zhe Xuan, Mingjin Shi, Yiwen Yang, Xianqiang Huang, Yifa Chen* and Ya-Qian Lan*. Angewandte Chemie International Edition, 2025, 64, e202417439.

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421

Hydrogen-localization Transfer Regulation in 3D COFs Enhances Photocatalytic Acetylene Semi-hydrogenation to Ethylene

Pei Huang, Ming-Yi Yang, Shuai-Bing Zhang, Ze-Hui Li, Han Zhang, Si-Miao Wang, Yan-Yu Peng, Mi Zhang*, Shun-Li Li, Meng Lu* and Ya-Qian Lan*. Angewandte Chemie International Edition, 2025, 64(13): e202423091.

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420

Crystal-Facet-Controlled Internal Electric Field in MOF/COF Heterojunction towards Efficient Photocatalytic Overall Water Splitting

Xiaoyu Chu, Shikai Liu, Bing-Bing Luan, Ying Zhang, Yuming Xi, Lu-Hua Shao, Feng-Ming Zhang* and Ya-Qian Lan*. Angewandte Chemie International Edition, 2025, 64(18): e202422940.

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419

Engineering Covalent Organic Frameworks for Photocatalytic Overall Water Vapor Splitting

Jin-Da Qu, Ya Wang, Ting-Ting Sun, Xiao-Yu Chu, Yan-Xia Jiang, Nan-Nan Zhang, Zhi-Hao Zhao, Hong Dong*, Ya-Qian Lan and Feng-Ming Zhang*. Angewandte Chemie International Edition, 2025, 32(35): 2503531.

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418

Charge-Transport Divergence in Ultrastable Heterometal-Oxo Clusters Exerting Significant Effect on Photoreactivity

Jing-Wen Shi, Ning Li, Yan Liang, Shan Xu, Long-Zhang Dong, Dongdi Zhang*, Jingyang Niu, Run-Han Li*, Jiang Liu, Shun-Li Li* and Ya-Qian Lan*. Angewandte Chemie International Edition, 2025, 137(22): e202502654.

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417

Interweaved Nanofiber Anode Coating Based on Covalent Organic Frameworks for High-Performance Lithium-Metal Batteries

Huifen Zhuang, Can Guo, Wenhai Feng, Liwen Wang, Zixi Zheng, Qi Li, Haifu Zhang, Yifa Chen* and Ya-Qian Lan*. Angewandte Chemie International Edition, 2025, 64, e202505626.

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416

Plasmonic Ion Diode Membrane (PIDM) for Enhanced Nanofluidic Ion Transport and Osmotic Energy Harvesting

Jia-Nan Chang, Kun Yang, Li-Na Wang, Jin Wang, Ya-Qian Lan* and Chen Wang*. Angewandte Chemie International Edition, 2025, 64, e202502591.

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415

One-Dimensional Covalent Organic Frameworks: From Design, Synthesis to Applications

Pei Huang , Lu-Hua Hou, Ming-Yi Yang, Cheng Xiao, Yan-Li Wu, Si-Jing Cai, Wen-Jie Guo, Mi Zhang*, Meng Lu* and Ya-Qian Lan*. Angewandte Chemie International Edition, 2025, 64, e202507002.

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414

Post-synthetic Rhodium (III) Complexes in Covalent Organic Frameworks for Photothermal Heterogeneous C-H Activation

Ke-Wei Tong, Yan-Hu Wang, Jing Du*, Chao-Qin Chen, Ya-Qian Lan* and Peng Yang*. Angewandte Chemie International Edition, 2025, 54, 5912-5960.

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413

Three-Motif Molecular Junction Covalent Organic Frameworks for Symmetric All-Organic Lithium-Ion Battery

Wenhai Feng, Zhi Yang, Can Guo, Huifen Zhuang, Rui Xu, Haifu Zhang, Mingjin Shi, Zhengyang Chen, Yifa Chen* and Ya-Qian Lan. Angewandte Chemie International Edition, 2025, 64, e202508937.

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412

Reticular Synthesis of 3D Metal Cluster-based COFs with Record High-Connectivity for Efficient Photocatalytic H2O2 Synthesis

Mi Zhang, Ming-Hao Qin, Run-Han Li, Ying-Ying Huang, Pei Huang, Yan-Yu Peng, Si-Miao Wang, Yong Yan*, Meng Lu* and Ya-Qian Lan*. Angewandte Chemie International Edition, 2025, 64, e202507624.

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411

Covalent Organic Framework Quantum Dots for Near-frictionless Ion Transport Battery Electrolyte

Can Guo, Pan Xue, Wenhai Feng, Yiwen Yang, Luanhua Zhou, Huifen Zhuang, Yuting Chen, Yifa Chen* and Ya-Qian Lan*. Angewandte Chemie International Edition, 2025, 137(39): e202512031.

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410

Molecular Junction Polyoxotungstate‐based Copper‐Organic Frameworks for Photocatalytic Cross‐Dehydrogenative Coupling

Zongyin Gao, Fei Yu, Meiyu Zhang, Xianqiang Huang*, Shiqi Fu , Mohammad Azam , Guodong Shen, Qingxia Yao, Qingde Zhang, Yifa Chen* and Ya-Qian Lan*. Angewandte Chemie International Edition, 2025, 64, e202516079.

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409

Conductive Knitting of Covalent Organic Framework Manipulates Spin Density, Orbital Reorganization, and Charge Mobility for Outstanding Photoreactivity

Qian‐Qian Huang, Ning Li*, Man‐Shi Han, Jiang Liu* and Ya‐Qian Lan*. Angewandte Chemie International Edition, 2025, 64, e202513848.

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408

Operando XAFS Reveals Dynamic Structural Evolution of Pt Single-Atom Catalysts for Efficient Chlorine Electrosynthesis

Qing Wang, Yun‐Bin Liao, Bingbao Mei, Jie Zhang, Daiki Kido, Weiren Cheng, Guangbo Chen, Tierui Zhang, Yitao Cao, Shun‐Li Li, Yong Yan* and Ya‐Qian Lan*. Angewandte Chemie International Edition, 2025, 64, e202513656.

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407

Precise Pore Engineering at Picometer Scale on Nanofluidic Membrane for Efficient Hydrogen Purification

Huijie Wang ,   Chong Wang ,   Jiang Liu ,   Ya‐Qian Lan* ,   Chen Wang*. Angewandte Chemie International Edition, 2025, 64, e202518187.

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406

Indole‐Linkages as Base‐Activated Sites in a Covalent Organic Framework for Efficient Photosynthesis of Hydrogen Peroxide Under Alkaline Conditions

Jinglun Yang ,   Yue Liu ,   Zihao Chen ,   Lei Zhang ,   Yanwei Zhao ,   Dong‐Sheng Li,   Furong Chen,   Ya‐Qian Lan*,   Qichun Zhang*. Angewandte Chemie International Edition, 2025, e22298.

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405

Efficient Solar-Driven Electrocatalytic Halogen-Mediated Ethylene Oxidation in Seawater by Metallophthalocyanine-Based COFs

Han Zhang, Yixin Ouyang, Wen-Jie Guo, Mi Zhang, Ze-Hui Li, Ming-Yi Yang, Pei Huang, Man-Zi Lv, Yu-Chen Zhong, Yun Zhang*, Meng Lu* and Ya-Qian Lan*. Angewandte Chemie International Edition, 2025, e20607.

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404

Pendant Group Design Toward Molecular Packing of Metal-Organic Frameworks Nanosheets in Micrometer-Scale for Photo-Thermal Catalysis

Yi-Lu Yang, Tao-Yuan Yu, Ying-Ying Huang, Qi Li, Jia-Min Ke, Shuai-Bing Zhang, Ming-Jie Long, Yong Yan, Yifa Chen* andYa-Qian Lan*. Angewandte Chemie International Edition, 2025, e24975.

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403

Subtle Tuning of Catalytic Well Effect in Phthalocyanine Covalent Organic Frameworks for Selective CO2 Electroreduction into C2H4

Yi-Lu Yang, Qi Li, Ping Liu, Qing Xu, Qi-Yi Zeng, Yu-Xin Chen, Yu-Qing Yang, Hao-Tao Yang, Fei Yu*, Yi-Rong Wang*, Yifa Chen* and Ya-Qian Lan. Advanced Materials, 2025, 37(4): 2415799.

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402

Predesign of Covalent-Organic Frameworks for Efficient Photocatalytic Dehydrogenative Cross-Coupling Reaction

Yu Chen, Sheng-Nan Sun, Xiao-Hong Chen, Ming-Lin Chen, Jiao-Min Lin*, Qian Niu, Shun-Li Li, Jiang Liu* and Ya-Qian Lan*. Advanced Materials, 2025, 37(6): 2413638.

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401

Steering Yolk–Shell Nanostructures of 1D Unit‐Based Covalent Organic Frameworks as Binder Modulators

Yiwen Yang, Fengxue Duan, Xiaoman Yao, Zhe Xuan, Xuanxu Chen, Mingjin Shi, Zhengyang Chen, Taoping Huang, Yifa Chen* and Ya-Qian Lan*. Advanced Materials, 2025, 37, 2505206.

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399

3D N-Heterocyclic Covalent Organic Frameworks for Urea Photosynthesis from NH3 and CO2

Ning Li, Jiale Zhang, Xiangdong Xie, Kang Wang*, Dongdong Qi*, Jiang Liu, Ya-Qian Lan and Jianzhuang Jiang*. Nature Communications, 2025, 16: 1106.

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398

An In-Situ Assembled Cobweb-Like Adhesive with High Processability

Xiaoming Xie, Runhan Li, Yongsheng Qiao, Jiaqi Zhang, Zilin Zhang, Xingyu Xu, Jie Yang, Yan-Yu Peng, Yifa Chen*, Shun-Li Li and Ya-Qian Lan*. Nature Communications, 2025, 16, 4872.

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397

Underscoring Covalent Organic Frameworks as Nano-Engines for Zinc Anode Protection Coating

Can Guo, Pan Xue, Fengxue Duan, Yifa Chen* and Ya-Qian Lan*. Accounts of Chemical Research, 2025, e202403918.

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396

Conjugated Phthalocyanine Based Framework as Artificial SEI for over 400 Wh kg−1 Lithium Metal Battery

Ying Zang, Peng Peng, Fei Pei*, Run-Han Li, Lin Wu, Di-Qiu Lu, Yi Zhang, Kai Huang, Yue Shen, Yun-Hui Huang* and Ya-Qian Lan*. National Science Review, 2025, 12(2): nwae443.

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395   

Facile Structuring of Crystalline Porous Framework Beads for Deep Purification of Nuclear Wastewater

Hai-Ruo Li, Xue-Zhuo Jing, Chao-Yue Zhao, Cheng-Peng Li* and Ya-Qian Lan*. National Science Review, 2025, 12(5): nwaf080.

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394

Asymmetric Heterogeneous Catalysis Using Crystalline Porous Materials

Teng Li, Yan-Ting Chen, Xiao-Bin Zhang, Rong-Rong Du, Lin-Na Ma and Ya-Qian Lan*. Chemical Society Reviews, 2025,54, 5912-5960.

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393

3D Interpenetrated Covalent Organic Frameworks

Jia-Yong Weng, Ming Yue, Qi Li, Yiwen Yang, Yi-Rong Wang*, Yifa Chen*, Shun-Li Li and Ya-Qian Lan*. Coordination Chemistry Reviews, 2025, 535: 216614.

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392     

Delving into Different Roles of Covalent Organic Frameworks in Zinc-Ion Batteries and Zinc-Air Batteries: A State-of-Art Review

Yuluan Zhang, Yi-Rong Wang, Luanhua Zhou, Can Guo, Mingjin Shi, Zhengyang Chen, Yuan Tian*, Yifa Chen* and Ya-Qian Lan*. Coordination Chemistry Reviews, 2025, 216670.

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391

Bidirectionally Tuned C(sp3)-H and N-H Photo-activation with Wurster-Type Covalent Organic Frameworks

Tao-Yuan Yu, Qian Niu, Tao Jiang, Jing-Wen Shi, Qi Li, Qing Huang, Yifa Chen*,   Shun-Li Li and Ya‐Qian Lan*. Science Bulletin, 2025, 70(21): 3479-3483.

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390

Achieving High-Efficient Carbon Radical-Mediated Cross-Coupling Reaction by Confined Radical Microenvironment in Metal-Organic Framework

Ying-Lin Li, Ning Li*, Zhi-Bin Mei, Jun-Rong Li, Su-Juan Yao, Fei Yu, Shun-Li Li, Jiao-Min Lin*, Jiang Liu* and Ya-Qian Lan. Chemical Science, 2025, 16, 11939-11948.

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389

Molecular weaving towards metalloporphyrin polymer coatings with integrated high stiffness and flexibility for anti-SARS-CoV-2 application

Xiaoman Yao ,   Jie Han ,   Xuanxu Chen ,   Caier Huang ,   Mingjin Shi ,   Qiuhua Wei ,   Xiaojie Ma* ,   Qian-You Wang ,   Tao Wang ,   Yifa Chen* ,   Bo Wang* ,   Ya-Qian Lan*. Inorganic Chemistry Frontiers, 2025,12, 8767-8775.

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388

Multifunctional Engineering and Active Sites Regulation of Covalent Organic Frameworks for Efficient Electrocatalytic Acetylene Hydrogenation to Ethylene

Ze-Hui Li, Han Zhang, Ming-Yi Yang, Shuai-Bing Zhang, Mi Zhang*, Yu-Fei Liu, Shun-Li Li, Meng Lu* and Ya-Qian Lan*. ACS Catalysis, 2025, 15(6): 4837-4844.

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387

Redox Heterocluster-Based Frameworks for One-Pot Photocatalytic C(sp3)-H Bond Oxidative Imination

Yu-Yang Liu, Shan Xu, Xiao-Xin Li, Run-Han Li, Xin-Ting Cai, Hui-Zhen Zhong, Jiang Liu, Qing Huang, Lei Zhang*, Shun-Li Li and Ya‐Qian Lan*. ACS Catalysis, 2025, 15(18): 16084-16093.

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386

Atomically Precise Metal–Metal Oxide Interface in Polyoxometalate-Noble Metal Hybrid Clusters

Hai-Ning Wang, Xing Meng*, Yitao Cao*, Shun-Li Li and Ya-Qian Lan. Small, 2025, 21(3): 2408884.

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385

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384

Bismuth‐Based Metal‐Organic Frameworks for Water Vapor Capture and Energy Storage

Jianxin Ma, Chen Wang, Qianqian Liu, Xinyu Chen, Bo Li, Zhong‐Min Su*, Ya-Qian Lan* and Hong‐Ying Zang*. Advanced Functional Materials, 2025, 35(15): 2419752.

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383

In situ Doping Coupling With Vacancy Regulation Induced Strong Metal-Support Interaction in Ni/CaTiO3 to Boost Supercharged Photothermal CO2 Methanation

Zhimin Yuan, Baokun Zhang, Xianglin Zhu, Shenghua Wang, Wei Sun, Baibiao Huang, Zaiyong Jiang*, Ying Dai, Zheng Wang, Wei Wei*, Xishi Tai* and Ya-Qian Lan*. Advanced Functional Materials, 2025: 2503531.

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Frontiers in Polyoxometalate-Based Hybrids for Photothermal Catalysis

Xiaofei Chen, Qianqian Li, Meijie Li, Mingjin Shi, Minqiao Liang, Yifa Chen*, Feng Bai* and Ya‐Qian Lan*. Advanced Functional Materials, 2025, e10863.

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381

Modulating Micro‐Environments in Tri‐Motif Molecular Junction COF for to Boost Photocatalytic CO2 Reduction

Jinxian Cui ,   Lu‐Yao Wang ,   Xiang Wang ,   Yaru Gong ,   Shuixing Wu ,   Yingjie Hua ,   Zi‐Yan Zhou ,   Jie Zhou* ,   Ya‐Qian Lan*. Advanced Functional Materials, 2025, e21214.

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380

Subtle Tuning of Micro-Environment in COFs Nanoribbons Actuates Low Electricity-Consumption Photo-Assisted Co-Electrolysis of Methanol and CO2

Yi-Rong Wang, Hui-Min Ding, Ming Yue, Qi Li, Jing-wen Shi, Qing Huang, Jie Zhou, Ying Zang*, Yifa Chen*, Shun-Li Li and Ya-Qian Lan*. Nano Research Energy, 2025, 4(1): e9120146.

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379

Redox and Conductive Covalent-Organic Binding Agent Boosts Sulfur Conversion Kinetics in Li-S Batteries

Taoping Huang, Xiaoman Yao, Xuanxu Chen, Minqiao Liang, Mingjin Shi, Yiwen Yang, Fei Yu, Fengxue Duan*, Yifa Chen* and Ya-Qian Lan. Chinese Chemical Letters, 2025, 111414.

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378

Atomic-level engineering of "one-pore one-cluster" architectures in covalent organic frameworks for C-C coupling reaction

Jinxian Cui, Jie Li, Xiang Wang, Jing-Wen Shi, Teng Li, Ying-jie Hua, Ya-Qian Lan and Jie Zhou*. Chinese Chemical Letters, 2025, 112164.

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377

Multi-metal-variate Covalent Organic Frameworks as Redox Mediators for Indirect Electrocatalytic S-S Bond Construction

Ming Yue, Gang Liu, Yixin Ouyang, Jia-Li Zhang, Jia-Yong Weng, Bingchuan Yang, Xianqiang Huang, Yi-Rong Wang*, Yifa Chen* and Ya‐Qian Lan*. Nano Research Energy, 2025, 4(4): e9120205.

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